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When I was a kid, I remember going to the movies and being wowed and amazed by special effects stop motion, blue screen, animated laser combat, matte paintings and while I m sure a lot of people were just thinking things like wow and cool, I was thinking I wish I could do that I was intrigued by the possibilities of trick photography, and I wanted to be able to do it myself Such special effects have always been possible for anyone with the time, money, equipment, and determination I had none of the above But when I got my first image-processing program in 1987, I realized I could finally do what I d always wanted to special effects and trick photography on a budget Indeed, digital photography opens a lot of doors for us mere mortals In this chapter, I tell you how to do some of the tricks that can make your images go beyond simple reality You may not want to try all the techniques in this chapter, but I think there s a little fun in here for just about everyone

M, Mi,

Table 12-2 lists six of the seven basic comparison operators that you can overload. Each entry includes a buddy value that identifies the matching operator that must also be overloaded.

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Property values in the standard state are denoted by the degree symbol For example, C; is the standard-state heat capacity Since the standard state for gases is the ideal-gas state, C; for gases is identical with CAg, and the data of Table Cl apply to the standard state for gases All conditions for a standard state are fixed except temperature, which is always the temperature of the system Standard-state properties are therefore functions of temperature only The standard state chosen for gases is a hypothetical one, for at 1 bar actual gases are not ideal However, they seldom deviate much from ideality, and in most instances enthalpies for the real-gas state at 1 bar and the ideal-gas state are little different When a heat of reaction is given for a particular reaction, it applies for the stoichiometric coefficients as written If each stoichiometric coefficient is doubled, the heat of reaction is doubled For example, the ammonia synthesis reaction may be written:

The symbol A Hiog8 indicates that the heat of reaction is the standard value for a temperature of 29815 K (25 C)

What is a blue screen Well, it s the generic term for a technique in which action is photographed or filmed in front of a solid-colored backdrop Later, in postproduction, special-effects technicians

Public Shared Widening Operator CType( _ ByVal operand1 As Bumblebee) As Integer ' ----- Perform conversion here. Return operand1.Bees End Operator End Class

Tabulation of data for just the standard heats of reaction for all of the vast number of possible reactions is impractical Fortunately, the standard heat of any reaction can be calculated if the standard heats offormation of the compounds taking part in the reaction are known A formation reaction is defined as a reaction which forms a single compound from its constituent elements For example, the reaction C + ;o2+ 2Hz + CH30H is the formation reaction for methanol The reaction H 2 0 + SO3 --+ H2S04is not a formation reaction, because it forms sulfuric acid not from the elements but from other compounds Formation reactions are understood to result in the formation of 1 mol of the compound; the heat of formation is therefore based on 1 mol of the compound formed Heats of reaction at any temperature can be calculated from heat-capacity data if the value for one temperature is known; the tabulation of data can therefore be reduced to the compilation of standard heats of formation at a single temperature The usual choice for this temperature is 29815 K or 25 C The standard heat of formation of a compound at this temperature is represented by the symbol AH&, The degree symbol indicates that it is the standard value, subscript f shows that it is a heat of formation, and the 298 is the approximate absolute temperature in kelvins Tables of these values for common substances may be found in standard handbooks, but the most extensive compilations available are in specialized reference works9 An abridged list of values is given in Table C4 of App C

example, see TRC Thermodynamic Tables-Hydrocarbons and TRC Thermodynamic Tables-Nonhydrocarbons, serial publications of the Thermodynamics Research Center, Texas A & M Univ System, College Station, Texas; "The NBS Tables of Chemical Thermodynamic Properties," J Physical and Chemical Reference Data, vol 11, supp 2, 1982 See also, T E Daubert et al, op cit Where data are unavailable, estimates based only on molecular structure may be found by the methods of L Constantinou and R Gani, Fluid Phase Equilibria, vol 103, pp 11-22, 1995

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