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When chemical equations are combined by addition, the standard heats of reaction may also be added to give the standard heat of the resulting reaction This is possible because enthalpy is a property, and changes in it are independent of path In particular, formation equations and standard heats of formation may always be combined to produce any desired equation (not itself a formation equation) and its accompanying standard heat of reaction Equations written for this purpose often include an indication of the physical state of each reactant and product, ie, the letter g, 1, or s is placed in parentheses after the chemical formula to show whether it is a gas, a liquid, or a solid This might seem unnecessary since a pure chemical species at a particular temperature and 1 bar can usually exist only in one physical state However, fictitious states are often assumed for convenience Consider the reaction C02(g)+ H2(g)-+ CO(g) + H20(g)at 29815 K (25 C) This watergas-shift reaction is commonly encountered in the chemical industry, though it takes place only at temperatures well above 29815 K (25 C) However, the data used are for 29815 K (25"C), and the initial step in any calculation of heat effects concerned with this reaction is to evaluate the standard heat of reaction at 29815 K (25 C) The pertinent formation reactions and their heats of formation from Table C4 are:

The class is pretty simple; it exists to maintain a simple count of bees. But by overloading the addition, subtraction, multiplication, and CType operators, we can use instances of bees with a more natural syntax.

Though the term is blue screen, the color of the backdrop doesn t have to be blue In fact, it s commonly green For the most part, the blue screen can be any color you like

H2(g):

A H;298=

Dim studyGroup1 As New Bumblebee(20) Dim studyGroup2 As New Bumblebee(15) Dim swarmGroup As Bumblebee = studyGroup1 * studyGroup2 MsgBox("The swarm contains " & CInt(swarmGroup) & " bees.")

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Since the reaction is actually carried out entirely in the gas phase at high temperature, convenience dictates that the standard states of all products and reactants at 29815 K (25 C) be taken as the ideal-gas state at I bar, even though water cannot actually exist as a gas at these conditions Writing the formation reactions so that their sum yields the desired reaction, requires that the formation reaction for C 0 2 be written in reverse; the heat of reaction is then of opposite sign to the standard heat of formation: c o 2 ( ~-+ c(s) + 02(g) ) c(s>+ 9 2 ( g ) H2(g) + $2(g)

substitute a different scene in place of the blue screen So a scene that looks as if it happened in midair or in France or on the moon actually happened in front of a blue tarp Separate footage is added in place of the tarp, and voil That s movie magic We can achieve the same kind of results ourselves It helps to use a real blue screen a solid-colored backdrop that you can paint out afterwards with a different image but it s also possible to achieve good results with no preplanning at all

co(g)

Running this code correctly generates a 300-bee swarm and the message in Figure 12-2.

-+ H2O(g)

9 Position the mouse pointer over the center of the text, and then drag the text until it is positioned over the shadow text, offset just enough that it looks like a drop shadow

C02(g) + H2(g) -+ CO(g) + H20(g)

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